:= is for assignments, = is for equations. I think you are talking about the following system of equations (I don't know what that 1S[i] is doing in the assignment to b[i]: I deleted the 1.
By the way, don't reduce Digits below the default 10. It can cause severe roundoff-error problems. If you only want to see 6 digits of the answers, use the "Round screen display to" option in Options, Precision (under the Tools menu). In fact, I would actually increase Digits in this case, since it appears that your system is very ill-conditioned.
> s:=140:
T:=1:
M:=40:
N:=10:
k:=T/N:
h:=s/M:
r:=0.05:
W:=20:
for i from 0 to M do
S[i]:=i*h:
u[i,0]:=W:
od:
for j from 0 to N do
u[M,j+1]:=s:
u[0,j+1]:=0:
od:
for i from 1 to M do
a[i]:=(r*k*S[i]/h-k*S[i]^2/h^2);
b[i]:=S[i]^2*k/h^2;
c[i]:=-(0.5*r*k*S[i]/h+k*S[i]^2/h^2);
od:
eqs:= [seq(seq(u[i,j]=a[i]*u[i-1,j+1]+b[i]*u[i,j+1]+c[i]*u[i+1,j+1], j=0..N),i=1..M-1)];
Digits:= 20;
with(LinearAlgebra):
vars:= convert(indets(eqs),list);
A,b:= GenerateMatrix(eqs,vars):
X:= LinearSolve(A,b);
[seq(vars[i]=evalf(X[i],6), i=1..429)];
[u[1,1] = -231.037, u[1,2] = 1753.49, u[1,3] = -20301.6, u[1,4] = 178954., u[1,5] = -.184263e7, u[1,6] = .173651e8, u[1,7] = -.171938e9, u[1,8] = .165582e10, u[1,9] = -.161953e11, u[1,10] = .157034e12, u[1,11] = -.153006e13, u[2,1] = -420.524, u[2,2] = 3964.74, u[2,3] = -36913.6, u[2,4] = 372654., u[2,5] = -.354358e7, u[2,6] = .349184e8, u[2,7] = -.337160e9, u[2,8] = .329288e10, u[2,9] = -.319547e11, u[2,10] = .311207e12, u[2,11] = -.302478e13, u[3,1] = -242.235, u[3,2] = 3265.58, u[3,3] = -26697.7, u[3,4] = 286872., u[3,5] = -.264558e7, u[3,6] = .265149e8, u[3,7] = -.253646e9, u[3,8] = .249022e10, u[3,9] = -.240952e11, u[3,10] = .235048e12, u[3,11] = -.228246e13, u[4,1] = 147.826, u[4,2] = -360.924, u[4,3] = 5922.94, u[4,4] = -49494.7, u[4,5] = 515891., u[4,6] = -.484162e7, u[4,7] = .480331e8, u[4,8] = -.462091e9, u[4,9] = .452228e10, u[4,10] = -.438349e11, u[4,11] = .427183e12, u[5,1] = 372.207, u[5,2] = -3655.23, u[5,3] = 32310.6, u[5,4] = -334392., u[5,5] = .313972e7, u[5,6] = -.311529e8, u[5,7] = .299662e9, u[5,8] = -.293288e10, u[5,9] = .284274e11, u[5,10] = -.277039e12, u[5,11] = .269168e13, u[6,1] = 216.775, u[6,2] = -3429.65, u[6,3] = 27770.1, u[6,4] = -296833., u[6,5] = .274900e7, u[6,6] = -.274781e8, u[6,7] = .263254e9, u[6,8] = -.258236e10, u[6,9] = .249985e11, u[6,10] = -.243795e12, u[6,11] = .236775e13, u[7,1] = -157.230, u[7,2] = 134.345, u[7,3] = -3304.76, u[7,4] = 26946.9, u[7,5] = -280931., u[7,6] = .264049e7, u[7,7] = -.261689e8, u[7,8] = .251901e9, u[7,9] = -.246442e10, u[7,10] = .238923e11, u[7,11] = -.232812e12, u[8,1] = -375.199, u[8,2] = 3558.87, u[8,3] = -30793.9, u[8,4] = 321187., u[8,5] = -.300506e7, u[8,6] = .298730e8, u[8,7] = -.287056e9, u[8,8] = .281112e10, u[8,9] = -.272385e11, u[8,10] = .265501e12, u[8,11] = -.257931e13, u[9,1] = -221.384, u[9,2] = 3473.14, u[9,3] = -27978.5, u[9,4] = 298288., u[9,5] = -.276742e7, u[9,6] = .276322e8, u[9,7] = -.264891e9, u[9,8] = .259752e10, u[9,9] = -.251502e11, u[9,10] = .245247e12, u[9,11] = -.238200e13, u[10,1] = 148.847, u[10,2] = -38.5246, u[10,3] = 2209.47, u[10,4] = -17611.6, u[10,5] = 183608., u[10,6] = -.172838e7, u[10,7] = .171118e8, u[10,8] = -.164814e9, u[10,9] = .161189e10, u[10,10] = -.156300e11, u[10,11] = .152287e12, u[11,1] = 366.209, u[11,2] = -3500.43, u[11,3] = 29977.0, u[11,4] = -313844., u[11,5] = .293162e7, u[11,6] = -.291679e8, u[11,7] = .280150e9, u[11,8] = -.274420e10, u[11,9] = .265863e11, u[11,10] = -.259164e12, u[11,11] = .251764e13, u[12,1] = 215.895, u[12,2] = -3484.43, u[12,3] = 28003.2, u[12,4] = -298113., u[12,5] = .276850e7, u[12,6] = -.276268e8, u[12,7] = .264925e9, u[12,8] = -.259739e10, u[12,9] = .251514e11, u[12,10] = -.245245e12, u[12,11] = .238205e13, u[13,1] = -149.865, u[13,2] = -13.5462, u[13,3] = -1603.56, u[13,4] = 12453.4, u[13,5] = -129940., u[13,6] = .122469e7, u[13,7] = -.121145e8, u[13,8] = .116740e9, u[13,9] = -.114140e10, u[13,10] = .110696e11, u[13,11] = -.107844e12, u[14,1] = -365.410, u[14,2] = 3459.69, u[14,3] = -29441.6, u[14,4] = 308920., u[14,5] = -.288298e7, u[14,6] = .286978e8, u[14,7] = -.275563e9, u[14,8] = .269966e10, u[14,9] = -.261527e11, u[14,10] = .254949e12, u[14,11] = -.247663e13, u[15,1] = -216.714, u[15,2] = 3485.61, u[15,3] = -27970.3, u[15,4] = 297482., u[15,5] = -.276433e7, u[15,6] = .275753e8, u[15,7] = -.264484e9, u[15,8] = .259277e10, u[15,9] = -.251082e11, u[15,10] = .244816e12, u[15,11] = -.237793e13, u[16,1] = 146.346, u[16,2] = 47.0026, u[16,3] = 1216.18, u[16,4] = -9149.90, u[16,5] = 95660.0, u[16,6] = -902441., u[16,7] = .892036e7, u[16,8] = -.859968e8, u[16,9] = .840612e9, u[16,10] = -.815355e10, u[16,11] = .794289e11, u[17,1] = 361.037, u[17,2] = -3428.08, u[17,3] = 29051.9, u[17,4] = -305273., u[17,5] = .284726e7, u[17,6] = -.283510e8, u[17,7] = .272187e9, u[17,8] = -.266684e10, u[17,9] = .258334e11, u[17,10] = -.251844e12, u[17,11] = .244642e13, u[18,1] = 214.115, u[18,2] = -3482.31, u[18,3] = 27916.8, u[18,4] = -296719., u[18,5] = .275839e7, u[18,6] = -.275093e8, u[18,7] = .263886e9, u[18,8] = -.258671e10, u[18,9] = .250507e11, u[18,10] = -.244249e12, u[18,11] = .237245e13, u[19,1] = -146.333, u[19,2] = -70.2692, u[19,3] = -945.551, u[19,4] = 6834.98, u[19,5] = -71705.3, u[19,6] = 676892., u[19,7] = -.668677e7, u[19,8] = .644876e8, u[19,9] = -.630229e9, u[19,10] = .611365e10, u[19,11] = -.595530e11, u[20,1] = -359.965, u[20,2] = 3402.46, u[20,3] = -28749.2, u[20,4] = 302401., u[20,5] = -.281931e7, u[20,6] = .280788e8, u[20,7] = -.269543e9, u[20,8] = .264110e10, u[20,9] = -.255831e11, u[20,10] = .249409e12, u[20,11] = -.242275e13, u[21,1] = -214.230, u[21,2] = 3477.20, u[21,3] = -27856.2, u[21,4] = 295932., u[21,5] = -.275191e7, u[21,6] = .274398e8, u[21,7] = -.263245e9, u[21,8] = .258029e10, u[21,9] = -.249892e11, u[21,10] = .243646e12, u[21,11] = -.236662e13, u[22,1] = 144.253, u[22,2] = 87.6008, u[22,3] = 744.761, u[22,4] = -5111.33, u[22,5] = 53918.6, u[22,6] = -509155., u[22,7] = .502717e7, u[22,8] = -.484978e8, u[22,9] = .473876e9, u[22,10] = -.459739e10, u[22,11] = .447805e11, u[23,1] = 357.177, u[23,2] = -3380.84, u[23,3] = 28503.5, u[23,4] = -300045., u[23,5] = .279650e7, u[23,6] = -.278561e8, u[23,7] = .267381e9, u[23,8] = -.262005e10, u[23,9] = .253785e11, u[23,10] = -.247418e12, u[23,11] = .240338e13, u[24,1] = 212.628, u[24,2] = -3471.23, u[24,3] = 27794.0, u[24,4] = -295163., u[24,5] = .274539e7, u[24,6] = -.273711e8, u[24,7] = .262606e9, u[24,8] = -.257392e10, u[24,9] = .249281e11, u[24,10] = -.243046e12, u[24,11] = .236081e13, u[25,1] = -144.002, u[25,2] = -101.019, u[25,3] = -589.183, u[25,4] = 3770.67, u[25,5] = -40121.4, u[25,6] = 378844., u[25,7] = -.373897e7, u[25,8] = .360805e8, u[25,9] = -.352488e9, u[25,10] = .342004e10, u[25,11] = -.333109e11, u[26,1] = -356.168, u[26,2] = 3362.21, u[26,3] = -28297.7, u[26,4] = 298055., u[26,5] = -.277730e7, u[26,6] = .276682e8, u[26,7] = -.265560e9, u[26,8] = .260231e10, u[26,9] = -.252061e11, u[26,10] = .245740e12, u[26,11] = -.238707e13, u[27,1] = -212.535, u[27,2] = 3464.97, u[27,3] = -27732.7, u[27,4] = 294427., u[27,5] = -.273903e7, u[27,6] = .273049e8, u[27,7] = -.261986e9, u[27,8] = .256775e10, u[27,9] = -.248689e11, u[27,10] = .242466e12, u[27,11] = -.235519e13, u[28,1] = 142.567, u[28,2] = 111.800, u[28,3] = 464.615, u[28,4] = -2693.05, u[28,5] = 29060.0, u[28,6] = -274222., u[28,7] = .270556e7, u[28,8] = -.261146e8, u[28,9] = .255090e9, u[28,10] = -.247523e10, u[28,11] = .241074e11, u[29,1] = 354.152, u[29,2] = -3345.81, u[29,3] = 28121.3, u[29,4] = -296336., u[29,5] = .276077e7, u[29,6] = -.275062e8, u[29,7] = .263991e9, u[29,8] = -.258701e10, u[29,9] = .250575e11, u[29,10] = -.244294e12, u[29,11] = .237301e13, u[30,1] = 211.410, u[30,2] = -3458.65, u[30,3] = 27673.4, u[30,4] = -293728., u[30,5] = .273293e7, u[30,6] = -.272418e8, u[30,7] = .261392e9, u[30,8] = -.256187e10, u[30,9] = .248122e11, u[30,10] = -.241912e12, u[30,11] = .234982e13, u[31,1] = -142.255, u[31,2] = -120.661, u[31,3] = -362.286, u[31,4] = 1804.37, u[31,5] = -19960.7, u[31,6] = 188040., u[31,7] = -.185495e7, u[31,8] = .179081e8, u[31,9] = -.174905e9, u[31,10] = .169729e10, u[31,11] = -.165301e11, u[32,1] = -353.247, u[32,2] = 3331.20, u[32,3] = -27967.2, u[32,4] = 294825., u[32,5] = -.274628e7, u[32,6] = .273640e8, u[32,7] = -.262616e9, u[32,8] = .257359e10, u[32,9] = -.249272e11, u[32,10] = .243025e12, u[32,11] = -.236067e13, u[33,1] = -211.245, u[33,2] = 3452.43, u[33,3] = -27616.5, u[33,4] = 293068., u[33,5] = -.272710e7, u[33,6] = .271819e8, u[33,7] = -.260827e9, u[33,8] = .255628e10, u[33,9] = -.247583e11, u[33,10] = .241385e12, u[33,11] = -.234471e13, u[34,1] = 141.177, u[34,2] = 128.115, u[34,3] = 276.478, u[34,4] = -1056.29, u[34,5] = 12319.4, u[34,6] = -115573., u[34,7] = .114022e7, u[34,8] = -.110098e8, u[34,9] = .107518e9, u[34,10] = -.104344e10, u[34,11] = .101617e11, u[35,1] = 351.679, u[35,2] = -3318.02, u[35,3] = 27830.8, u[35,4] = -293479., u[35,5] = .273341e7, u[35,6] = -.272375e8, u[35,7] = .261393e9, u[35,8] = -.256165e10, u[35,9] = .248113e11, u[35,10] = -.241897e12, u[35,11] = .234971e13, u[36,1] = 210.391, u[36,2] = -3446.36, u[36,3] = 27562.1, u[36,4] = -292443., u[36,5] = .272156e7, u[36,6] = -.271251e8, u[36,7] = .260290e9, u[36,8] = -.255097e10, u[36,9] = .247072e11, u[36,10] = -.240885e12, u[36,11] = .233986e13, u[37,1] = -140.857, u[37,2] = -134.480, u[37,3] = -203.297, u[37,4] = 415.907, u[37,5] = -5793.05, u[37,6] = 53602.3, u[37,7] = -529458., u[37,8] = .511257e7, u[37,9] = -.499230e8, u[37,10] = .484518e9, u[37,11] = -.471842e10, u[38,1] = -350.872, u[38,2] = 3306.02, u[38,3] = -27708.4, u[38,4] = 292268., u[38,5] = -.272184e7, u[38,6] = .271237e8, u[38,7] = -.260293e9, u[38,8] = .255092e10, u[38,9] = -.247071e11, u[38,10] = .240882e12, u[38,11] = -.233984e13, u[39,1] = -210.201, u[39,2] = 3440.49, u[39,3] = -27510.2, u[39,4] = 291852., u[39,5] = -.271629e7, u[39,6] = .270712e8, u[39,7] = -.259781e9, u[39,8] = .254594e10, u[39,9] = -.246587e11, u[39,10] = .240411e12, u[39,11] = -.233526e13]